Hi! I have RPI4 wit OMV 5. I am facing a strange situation. It is possible to ping OMV, it is possible to access SMB shares via netbios name. But it is not possible to access the share via ip address. I have experienced opposite issues due to DNS settings before, but not like this one.
Client - WIndows 10 PC
It is possible to connect to SMB shares by ip address from ios devices (i have not tried others)/