As a follow up to this thread it is no longer possible using the GUI to add/create a btrfs file system on an mdadm raid (software raid), selecting btrfs from file systems you get the following;
Type -> BTRFS
Profile -> Single, DUP, Raid0, Raid1, Raid10
Devices -> self explanatory
under devices if you select an mdadm raid you will see "At least two devices are required" if you select a raid option from the profile drop down
The btrfs file system has moved to Profiles -> this site has some excellent information along with btrfs read the docs