I was using OMV from version 6 to 7 with ZFS and Windows VSS, and everything worked fine—until one day, VSS suddenly stopped working. When trying to access Previous Versions from Windows, OMV would hang completely, except for the web GUI. SMB shares and SSH would become unresponsive, and I had to power off OMV repeatedly just to troubleshoot.
So, my suggestion: if you plan to use ZFS, you might want to avoid OMV. I also hope that one day ZFS will be supported as a native file system in OMV, rather than just through a plugin.