The admin user is only used for web UI login and does not get any emails.
So I guess it is a software that has a UI and the user admin that is sending emails to you. You did never mention what the content of this emails is. It might help to identify the creator of those.
I have email notifications setup to go to admin@home (which works) but these emails were being sent to admin@macserve.home that I may have set up in OMV years ago, but switched to @home as @macserve.home did not work. So I'm wondering if this loop has been going on for years.
Unfortunately I was unable to actually look at any of the messages to help discover their origin.
Anyway, in my attempts to reconfigure postfix on the server, a small change to test something caused 517 emails to suddenly be delivered and the loop stopped. They were rejected mail error messages that have obviously been looping around for quite some time. Anyway the loop was broken and the network as as quiet as it should be.
Also, I have now been able to modify postfix to accept mails to user@macserve.home, so there should never be another loop.
Now I can get back to trying to figure out why my auto backup function is not working as it should and not sending me notification emails, which is what caused me to discover the loop.