I've added a lot of packages outside of the OMV UI and made countless tweaks as I've used the system. I do not believe screenshots would be sufficient to restore my configuration. I'm really thinking more either in-place installation or just doing nothing, because I have had no actual issues with it other than packages that aren't available on older debian. Not breaking anything that's currently working is my top priority, especially since I access a lot of the functionality via windows and stuff like SMB took forever to get working correctly.
Until just over a month ago, I too was stuck on OMV 5. And I've been in the same boat - having tweaked a lot of things outside of OMV itself, configured everything just the way I like it, etc. - so yes, the prospect of a completely fresh install is daunting.
But consider that even if your system is continuing to work just fine, eventually it won't. You've already missed out on security updates at the least, and something will come and bite you.
I spent the last month setting up OMV 7 from scratch (I prefer to wait for OMV8 to be stable and an upgrade path to become available before I go that route). It took a lot of time but was SO worth it. Many of the things I'd bolted on to the old OMV5 install I was able to reconfigure in a much cleaner way using the OMV7 GUI (for example, setting up a network bridge interface, WireGuard, moving Emby from host-level operation to a Docker container, even automatic updating of my SSL cert via acme.sh and update_cert.sh, etc.). As I've gained a lot of experience both with OMV and with Linux/Debian generally, I'm now happy with a more polished and up-to-date system. Most importantly, I'm back in the loop with functionality and security updates - AND a proper upgrade path. Then there's the plugins - there's a whole lot more of them than in OMV5. The KVM and Compose plugins alone are superb.
Consider these points. I recommend that you take the time for a fresh install and just go step by step. Maybe you can spare another computer as a temporary server in the meantime - I did this, too, by cloning the old OMV5 install to a mini-PC and some of my data copied to an external HDD.