You might reconsider how you use OMV. It is possible to install OMV to a thumbdrive and run it from there. Then you can backup your rootfs simply by backing up the thumbdrive. Google "image thumbdrive".
However, if you use OMV for other purposes than a simple NAS, then it may not be a good idea to run OMV from a thumbdrive.
Then, if you have OMV installed on a HDD or SSD, you can boot from some other media and backup OMV that way. You might use Clonezilla for instance. Or SystemRescue. Or any version of Linux with suitable backup or imaging tools. For instance rsync and dd.
https://clonezilla.org/
http://www.system-rescue-cd.org/
You boot from other media because it can be hard to reliably backup a running Linux root filesystem.
Google "backup root filesystem" for other techniques and tutorials.
I myself run several OMV servers from SD-cards. I just use OMV for the NAS functionality. I wrote a couple of scripts to backup and restore the SD-cards. Similar to imaging a USB drive.
On my Linux computers I dual boot to two separate Linux systems. One main and one small I only use to backup the main system, using only rsync. I store the rootfs backups on my OMV NAS servers.