Thanks a mil, this is the process I followed if it helps anyone and it seems to have worked:
I'd highly recommend reading up on each command and the options I selected to make sure they'll work as intended in your scenario.
Before:
root@openmediavault:~# pvscan
PV /dev/sda VG volumeGroup lvm2 [1.82 TiB / 0 free]
PV /dev/sdb VG volumeGroup lvm2 [1.82 TiB / 0 free]
PV /dev/sdc VG volumeGroup lvm2 [1.82 TiB / 0 free]
Total: 3 [5.46 TiB] / in use: 3 [5.46 TiB] / in no VG: 0 [0 ]
root@openmediavault:~#
I needed to remove /dev/sdc so I copied off as much as possible and was left with 2.2TB of data on my VG. These commands were run:
/etc/init.d/nfs-kernel-server stop
umount /dev/mapper/volumeGroup-MyDisk
resize2fs /dev/mapper/volumeGroup-MyDisk 2900G && e2fsck -f /dev/mapper/volumeGroup-MyDisk
lvreduce -L 3000G /dev/mapper/volumeGroup-MyDisk && e2fsck -f /dev/mapper/volumeGroup-MyDisk
resize2fs /dev/mapper/volumeGroup-MyDisk && e2fsck -f /dev/mapper/volumeGroup-MyDisk
pvmove /dev/sdc
vgreduce volumeGroup /dev/sdc
After:
root@openmediavault:~# pvscan
PV /dev/sda VG volumeGroup lvm2 [1.82 TiB / 0 free]
PV /dev/sdb VG volumeGroup lvm2 [1.82 TiB / 726.03 GiB free]
PV /dev/sdc lvm2 [1.82 TiB]
Total: 3 [5.46 TiB] / in use: 2 [3.64 TiB] / in no VG: 1 [1.82 TiB]
root@openmediavault:~#