The conclusion can only be an official fix anyway otherwise it would make no sense to offer mergerfs in the GUI in the first place when it's buggy like that.
This only seems to happen to people who upgraded from OMV5 and with the unionfs in use.
Which I believe is your case.
I'm not well versed on this but the constants are those and when the upgrade changes from UnionFS to MergerFS, something goes sideways.
What I've seen is also the check of "fstab" on the GUI gives issues.
After stopping the Pool and remove it, when recreating it without the fstab checked, it works.
Nonetheless, I'll poke Zoki and ryecoaaron since they're the ones sorting solutions to this issue.