There is no way to backup an OMV 4.x configuration (network, plugins, services, users...) and use it on another fresh install, regardless of the version of the new installation.
What you can do is use an unofficial method to upgrade your OMV 4.x installation to OMV 5. See:
https://forum.openmediavault.org/index.php/Thread/27909-ETA-for-OMV-5-0-weeks-months-quarters-2020/?postID=219830#post219830
Caveats:
You must uninstall all plugins on the OMV 4.x install that do not have a corresponding OMV 5.x plugin. It's possible to identify which ones to remove, but it is easier to just uninstall all of them, making a list of all installed plugins first, along with any notes you feel necessary to have when you install the plugins in your new OMV 5.x. Some OMV 4.x plugins have no ported to OMV 5 version, so you will need to find other ways to do the same things or use forum provided suggestions / workarounds.
You only get one shot at an in-place upgrade. If it fails for any reason and you do not have a verified to work method to restore an OMV 4.x full system backup (so you can try the upgrade again).........so much toast.
I did an in place upgrade of OMV 4.x to 5.x by first uninstalling all plugins from OMV 4.x, performing the cited upgrade, and then installing all the plugins into OMV 5. It worked without any major problems. DNS resolution breaks from time to time, but it's easy to fix when it does. No idea why this is happening but it never happened until I upgraded to OMV 5.