The guide setup should work fine in your home without CGNAT.
- What is the YML file or the container stack now, can you post it here? Skip sensitive data.
- Where has this message been recorded "The requested address cannot be assigned? In the portainer? In the syncthing record? It publishes the complete message.
- Is the OMV firewall GUI interface empty? If not, post it. Did you configure something in the CLI in iptables?